I stick to real symmetric matrices. I think the eigengen and eigensym use different algorithms to compute eigenvectors that's why there might be differences in sign for some eigenvectors.
I do not know the intrinsics of the algorithms so i cannot tell why patricular eigenvecs have the same and some have different sign.
However, due to sign being non-identified "it does not matter". You must have extra information to identify depending on your purposes.
The pca does not know what sign to assign. I think (correct me if i am wrong)
pca uses princomp which uses eigensym and not eigengen.